合成彩色立方氧化锆的宝石学特征

市场上出现的紫色、浅紫色、浅黄色、粉红色、酒黄色、黄褐色、红色人造立方氧化锆均为亚金刚光泽, 火彩明显; 密度为5.99～6.34 g/cm3, 相对硬度为8～9; 除粉红色者表现出非均质性和弱多色性且内含大量定向排列的白色脱溶物外, 其余的为均质性, 内部洁净; 不同颜色的立方氧化锆的吸收光谱、紫外荧光以及滤色镜下的变色情况均存在差异; 浅紫色立方氧化锆的吸收光谱特征表明它是Nd致色. 能谱分析结果表明: 彩色立方氧化锆的常见元素有Zr, Y, P, Hf, Ca等; Er, Ce, Fe分别是粉红色、红色、酒黄色立方氧化锆的致色元素; 当Y2O3的摩尔分数大于或近于7%时, 立方氧化锆为立方面心结构且内部洁净; 当Y2O3的摩尔分数小于5%时, 立方氧化锆表现为非均质性且内含大量定向分布的白色脱溶物. 用拉尔森改写的格拉斯顿-代尔公式计算其近似折射率为2.12～2.19.     

黑土土壤质量演变初探I：不同开垦年限黑土主要质量指标演变规律

根据土壤质量的定义和研究方法 ,对黑土的主要质量指标演变规律进行初步研究。结果表明 :黑土的颗粒组成受开垦历史影响的程度较小 ,其质地没有发生显著变化 ;黑土的有机质、全氮、全硫和全磷随着黑土开垦时间的增加而不断降低 ;速效磷随黑土开垦时间的增加有增高的趋势。经过统计分析 ,黑土中粉砂(0.05～0.002mm)含量与细砂(0.25～0.05mm)和粘粒(<0.002mm)含量具有相关性,黑土有机质含量与全氮、全硫、全磷和速效钾具有明显的正相关。因此 ,初步认为黑土中粉粒和有机质含量可以作为土壤物理和养分方面的质量指标     

DCS的评价与选择

本文综述了ＤＣＳ（集散控制系统）三代产品的总体水平评价，介绍了ＤＣＳ的总体性能、评价指标和它的选择准则。     

Solar radiation climate in Malawi

Recently, Diabaté et al. [Diabaté, L., Blanc, Ph., Wald, L., 2004. Solar climate in Africa. Solar Energy 76, 733–744] created a map of solar radiation climate in Africa using clearness index for 62 sites. They established a solar climate class II located in Malawi and Madagascar. However, their analysis did not include any irradiation data from a site in Malawi. In this study, the solar radiation climate of Malawi has been studied using long-term global radiation data from a local site. The mean monthly (K_tm) and seasonal (K_ts) daily clearness indices for the site were computed. It is observed that K_tm has two maxima in a year (K_tm = 0.58 in May and K_tm = 0.64 in September), in close conformity with findings of Diabaté et al. (2004). Other results are presented and discussed.     

Adsorption and decomposition of H2S on Pd(1 1 1) surface: a first-principles study

Gradient-corrected density functional theory was used to investigate the adsorption of H₂S on Pd(1 1 1) surface. Molecular adsorption was found to be stable with H₂S binding preferentially at top sites. In addition, the adsorption of other S moieties (SH and S) was investigated. SH and S were found to be preferentially bind at the bridge and fcc sites, respectively. The reaction pathways and energy profiles for H₂S decomposition giving rise to adsorbed S and H were determined. Both H₂S_(ad) → SH_(ad) + H_(ad) and SH_(ad) → S_(ad) + H_(ad) reactions were found to have low barriers and high exothermicities. This reveals that the decomposition of H₂S on Pd(1 1 1) surface is a facile process.     

铀工业指标研究的几个问题

本文介绍在铀矿床工业指标制定中,对未来矿山开采设计方案及经济计算参数几千问题的分析,以利于合理的制定铀矿床工业指标,为铀矿冶企业技术改造,在建企业修改设计和为选择新建企业提供决策依据,进而使铀矿冶企业提高经济效益。     

基于过程能力指数的刀具寿命研究

利用Glejser检验方法拟舍出刀具磨损过程残差模型，在此基础上，计算换刀时刻的过程能力指数，并且根据企业所要求的最低过程能力指数，计算刀具的质量寿命，提出将刀具的切削寿命和质量寿命结合起来进行换刀决策的方法。     

缝洞型碳酸盐岩油藏流动单元概念和研究方法探讨

流动单元对于提高油田采收率具有很大的实际意义,该项研究在砂岩油藏研究中已取得较大进展。对于缝洞型碳酸盐岩油藏,由于岩石结构构造、成岩后生作用、构造断裂作用、溶蚀作用等多因素对储集空间的影响,已有的流动单元概念及研究技术方法难于应用。以塔河油田为例,针对缝洞型碳酸盐岩地质特征,论证了碳酸盐岩储层渗流屏障的存在及其类型,探索性提出区别于砂岩油藏的缝洞型碳酸盐岩储层流动单元的概念。提出的研究思路和方法包括;油藏压力趋势分析法、井间生产干扰分析法、流体性质差异分析法、井间干扰试井法。结合储层发育特征,初步建立了缝洞型碳酸盐岩流动单元的划分标准。     

Structural reliability optimization using an efficient safety index calculation procedure

The objective of this paper is to conduct reliability-based structural optimization in a multidisciplinary environment. An efficient reliability analysis is developed by expanding the limit functions in terms of intermediate design variables. The design constraints are approximated using multivariate splines in searching for the optimum. The reduction in computational cost realized in safety index calculation and optimization are demonstrated through several structural problems. This paper presents safety index computation, analytical sensitivity analysis of reliability constraints and optimization using truss, frame and plate examples.     

激光探针监测半导体器件内自由载流子浓度调制效应

介绍了基于自由载流子对介质折射率调制作用,而建立的监测半导体器件内自由载流子变化情况的实验装置,该装置能实时反映自由载流子变化情况,且对原电路无任何影响。本方法适用于硅和砷化镓材料的电子和光电子器件,也显示了在测量集成电路内部有源器件特性方面的潜在应用前景。